some other errors:
1) <variableAgg name="dsp_band_1" /> names the field you want to aggregate
2) coordValue="1999-01-01T08:24:17Z", not coord="1999-01-01T08:24:17Z"
<catalog xmlns="http://www.unidata.ucar.edu/namespaces/thredds/InvCatalog/v1.0"
xmlns:xlink="http://www.w3.org/1999/xlink"
name="URI-THREDDS OPeNDAP Data Server" version="1.0.1">
<service name="opendap" serviceType="OPENDAP" base="/thredds/dodsC/" />
<dataset name="Pathfinder AVHRR Northwest Atlantic Aggregation (6km Declouded)"
urlPath="AVHRRAggregation.nc" ID="AVHRRAggregation">
<serviceName>opendap</serviceName>
<netcdf xmlns="http://www.unidata.ucar.edu/namespaces/netcdf/ncml-2.2">
<dimension name="time" length="0"/>
<variable name="time" type="String" shape="time" >
<attribute name="_CoordinateAxisType" value="Time" />
</variable>
<aggregation dimName="time" type="joinNew">
<variableAgg name="dsp_band_1" />
<netcdf
location="http://dods.gso.uri.edu/dods-3.4/nph-dods/Pathfinder/Northwest_Atlantic/6km/declouded/1999/1/f99001082417.hdf"
coordValue="1999-01-01T08:24:17Z" />
<netcdf
location="http://dods.gso.uri.edu/dods-3.4/nph-dods/Pathfinder/Northwest_Atlantic/6km/declouded/1999/1/f99001181038.hdf"
coordValue="1999-01-01T18:10:38Z" />
<netcdf
location="http://dods.gso.uri.edu/dods-3.4/nph-dods/Pathfinder/Northwest_Atlantic/6km/declouded/1999/1/f99001195049.hdf"
coordValue="1999-01-01T19:50:49Z" />
<netcdf
location="http://dods.gso.uri.edu/dods-3.4/nph-dods/Pathfinder/Northwest_Atlantic/6km/declouded/1999/1/f99002081244.hdf"
coordValue="1999-01-02T08:12:44Z" />
</aggregation>
</netcdf>
</dataset>
</catalog>